Structure and magnetism of new lanthanide 6-wheel compounds utilizing triethanolamine as a stabilizing ligand.
نویسندگان
چکیده
The reaction of Ln(NO(3))(3).6H(2)O (Ln = Gd, Dy) with triethanolamine (teaH(3)) and triethylamine in MeOH gives two isostructural hexanuclear wheels of formula [Ln(6)(teaH)(6)(NO(3))(6)].8MeOH, the magnetic properties of which show slow magnetisation relaxation in the Dy case.
منابع مشابه
مروروی بر تهیه و شناسایی ساختار کمپلکسهای تری اتانول امین
Up to date 12 complexes of triethanolamine with alkali, alkaline earth, lanthanide metals and hydrogen have been reponed. The synthesis and structure determination of these compounds is the subject of this review papacr. Moreover, the similarities and the differences of the complexes with respect to the metals and ligand are discussed.
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عنوان ژورنال:
- Dalton transactions
دوره 39 7 شماره
صفحات -
تاریخ انتشار 2010